Kinetically stabilized aromatic S-nitrothiols bearing bulky groups, 2,4,6-tri-t-butylphenyl (Mes*) and 4-t-butyl-2,6-bis[(2,2",6,6"-tetramethyl-m-terphenyl-2'-yl) methyl]phenyl group (Bmt) were prepared by the reaction of the corresponding thiols with t-butyl nitrite. The molecular structure of stable S-nitrothiol BmtSNO2 was established by X-ray crystallographic analysis. The reactions of S-nitorothiols Mes*SNO2 and BmtSNO2 with some nucleophiles and the thermolysis were reported.
雑誌書誌ID
収録物識別子タイプ
NCID
収録物識別子
AN10420713
書誌情報
日本女子大学紀要. 理学部
en : Journal of Japan Women's University. Faculty of science
KJ00004084534.pdf (472.7 kB)
